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libxml is a validating XML parser written in C (also known as gnome-xml). It has an event-based (SAX-like) interface and can also build an in-memory DOM-like tree of the parsed document. It can use XML Catalog to resolve entity references.
libxml has a full XPath implementation, and supports namespaces, XPointer, XInclude, SGML Open Catalogs, XML Catalog, RELAX-NG, and XML Schema 1&2. An HTML parser is also included.
A DOM implementation is available through Gdome.